Controlled Synthesis of Pt-Ni Bimetallic Catalysts and Study of Their Catalytic Properties

Author: Hagendorf, Col
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BISAC Categories:
Nanoscience |
This thesis focuses on the controlled synthesis of Pt-Ni bimetallic nanoparticles and the study of their catalytic properties. It discusses in detail the nucleation mechanism and the growth process of bimetallic systems, which is vital for a deeper understanding of the design of bimetallic catalysts. The author presents four pioneering studies: (1) syntheses of water-soluble octahedral, truncated octahedral, and cubic Pt-Ni nanocrystals and the study of their structure-activity relationship in model hydrogenation reactions; (2) a strategy for designing a concave Pt-Ni alloy using controllable chemical etching; (3) defect-dominated shape recovery of nanocrystals, which is a new synthesis strategy for trimetallic catalysts; (4) a sophisticated construction of Au islands on Pt-Ni, which is an ideal trimetallic nanoframe catalyst. This thesis inspires researchers working in materials, catalysis as well as other interdisciplinary areas.

Publisher Name Springer
Author Name Hagendorf, Col
Format Audio
Bisac Subject Major SCI
Language NG
Isbn 10 3662498456
Isbn 13 9783662498453
Target Age Group min:NA, max:NA
Series 000416125
Dimensions 00.92" H x 10.06" L x 14.00" W
Page Count 111

Area of work: synthesis of bimetallic nanocrystals and study of their catalytic properties
Degree:
9/2009-7/2014 Ph. D of Chemistry, Tsinghua University
9/2005-7/2009 B.S. of Chemistry, Tsinghua University
Awards:
2014 Honor of Excellent thesis in Tsinghua University
2014 Honor of Excellent graduate student in Beijing
2014 Principal Tsinghua scholarship (10 persons each year)
2014 and 2013: National Scholarship
2013 Best Poster Prize on Sino-US nano symposium
2013 JiaXi Lu Scholarship
2012 Aoqing Tang Scholarship
2012 The Ministry of Education Academic Newcomer Award
Publications:
[1] Wu Y E; Wang D S; Li Y D. Nanocrystals from Solutions: Catalysts. Chem. Soc. Rev. 2014, 43: 2112-2124.
[2] Wu Y E; Wang D S; Zhou G; Yu R; Chen C; Li Y D. Sophisticated Construction of Au Islands on Pt Ni: An Ideal Trimetallic Nanoframe Catalyst. J. Am. Chem. Soc. 2014, 136, (33): 11594-11597.
[3] Wu Y E; Wang D S; Chen X B, Zhou G; Yu R; Li Y D. Defect-Dominated Shape Recovery of Nanocrystals: A New Strategy for Trimetallic Catalysts. J. Am. Chem. Soc. 2013, 135, (33): 12220-12223.
[4] Wu Y E; Wang D S; Niu Z Q; Chen P C; Zhou G; Li Y D. A Strategy for Designing a Concave Pt Ni Alloy through Controllable Chemical Etching. Angew. Chem. Int. Edit. 2012, 51, (50): 12524-12528.
[5] Wu Y E; Cai S F; Wang D S; He W; Li Y D. Syntheses of Water-Soluble Octahedral, Truncated Octahedral, and Cubic Pt Ni Nanocrystals and Their Structure Activity Study in Model Hydrogenation Reactions. J. Am. Chem. Soc. 2012, 134, (21): 8975-8981. [6] Wu Y E; Wang D S; Zhao P; Niu Z Q; Peng Q; Li Y D. Monodispersed Pd-Ni Nanoparticles: Composition Control Synthesis and Catalytic Properties in the Miyaura-Suzuki Reaction. Inorg. Chem. 2011, 50, (6): 2046-2048."

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